22690-86-4Relevant academic research and scientific papers
Mono- and poly-nuclear copper(II) carboxylates with flourous ligands: Synthesis, structure and improved properties
Iqbal, Muhammad,Ali, Saqib,Tahir, Muhammad N.,Nawaz, Arif,Anderson, Paul A.,Khan, Wilayat
, (2019)
Polynuclear copper(II) complexes [Cu(para-fluorophenyl acetate)2]n (1) and [Cu(para-nitrophenyl acetate)2]n (2) were converted in-situ to mono-nuclear complexes [Cu(para-fluorophenyl acetate)2(1,10-Ph
Decarboxylative Benzylation of Aryl and Alkenyl Boronic Esters
Moon, Patrick J.,Fahandej-Sadi, Anis,Qian, Wenyu,Lundgren, Rylan J.
supporting information, p. 4612 - 4616 (2018/03/26)
The copper-catalyzed decarboxylative benzylation of aryl and alkenyl boronic esters with electron-deficient aryl acetates is reported. The oxidative coupling proceeds under mild, aerobic conditions and tolerates a host of potentially reactive electrophilic functional groups that would be problematic with traditional benzylation methods (aryl iodides and bromides, protic heteroatoms, aldehydes, Michael acceptors). A reaction pathway in which a benzylic nucleophile is generated by aryl acetate decarboxylation and in turn is intercepted by the catalyst to form diarylmethane products is supported by mechanistic studies.
