226993-35-7

Basic information

• Product Name: methyl 2-phenylacetyl-5-propyl-7-trimethylsilyl-hepta-6-ynoate
• Synonyms: methyl 2-phenylacetyl-5-propyl-7-trimethylsilyl-hepta-6-ynoate
• CAS NO: 226993-35-7
• Molecular Weight: 358.553
• Mol File: 226993-35-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2-phenylacetyl-5-propyl-7-trimethylsilyl-hepta-6-ynoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-phenylacetyl-5-propyl-7-trimethylsilyl-hepta-6-ynoate(226993-35-7)
• EPA Substance Registry System: methyl 2-phenylacetyl-5-propyl-7-trimethylsilyl-hepta-6-ynoate(226993-35-7)

Safety Data

• Hazardous Substances Data: 226993-35-7(Hazardous Substances Data)

Upstream product

• 614-27-7 methyl 3-oxo-3-phenylpropionate 
• 226993-21-1 [3-(2-bromo-ethyl)-hex-1-ynyl]-trimethyl-silane 
• 693-02-7 hex-1-yne 
• 226993-09-5 3-propyl-5-trimethylsilyl-pent-4-yn-1-ol 

Downstream Products

• 226993-45-9 methyl 2-phenylacetyl-5-propyl-hepta-6-ynoate 

Relevant articles and documents

Cobalt-mediated cycloisomerization of δ-substituted ε-acetylenic β- ketoesters construction of angular triquinane by a sequence ene/Pauson-Khand reactions

The preparation of δ-substituted ε-acetylenic β-ketoesters is fully described. Their cobalt-mediated Conia-ene reactions led to variously functionalized methylenecyclopentanes in high yields land with a moderate control of the 1,4 diastereoselectivity. A sequence involving the cobalt- mediated ene and Pauson-Khand reactions is presented and allowed the construction of the angular triquinane framework.