227766-19-0Relevant academic research and scientific papers
Efficient amination of sulfides with a ketomalonate-derived oxaziridine: application to [2,3]-sigmatropic rearrangements of allylic sulfimides.
Armstrong, Alan,Cooke, Richard S
, p. 904 - 905 (2007/10/03)
A novel N-Boc-oxaziridine is reported, derived from diethyl ketomalonate, which effects efficient amination of sulfides to sulfimides. The reagent is applied to the [2,3]-sigmatropic rearrangement of allylic sulfimides.
The preparation of N-tert-butyloxycarbonyl-(Boc-)protected sulfoximines and sulfimines by an iron(II)-mediated nitrene transfer from BocN3 to sulfoxides and sulfides
Bach, Thorsten,Koerber, Christina
, p. 1033 - 1039 (2007/10/03)
The imidation of sulfides and sulfoxides to the corresponding sulfimides and sulfoximides was carried out with N-tert-butyloxycarbonyl azide (BocN3) in the presence of FeCl2. Sulfoxides 1 reacted at room temperature in CH2
