227960-37-4

Basic information

• Product Name: NiCl₂(P(C₆H₅)CH₂N(CH₂C₆H₅)CH₂)2
• CAS NO: 227960-37-4
• Molecular Weight: 612.141
• Mol File: 227960-37-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: NiCl₂(P(C₆H₅)CH₂N(CH₂C₆H₅)CH₂)2(CAS DataBase Reference)
• NIST Chemistry Reference: NiCl₂(P(C₆H₅)CH₂N(CH₂C₆H₅)CH₂)2(227960-37-4)
• EPA Substance Registry System: NiCl₂(P(C₆H₅)CH₂N(CH₂C₆H₅)CH₂)2(227960-37-4)

Safety Data

• Hazardous Substances Data: 227960-37-4(Hazardous Substances Data)

Upstream product

• 80363-59-3 1,5-dibenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane 

Relevant articles and documents

Synthesis and structural studies of molybdenum and palladium complexes of 1,5-diaza-3,7-diphosphacyclooctane ligands

1,5-Diaza-3,7-diphosphacyclooctanes form 1:1 complexes with the metal fragments Mo(CO)4 and PdCl2. Two of these products along with a parent heterocycle have been structurally characterized. The [P(Ph)CH2N(2-pyridyl)CH2]2 ring is found in a crown conformation while its cis-Mo(CO)4 complex adopts a chair-boat ligand conformation. On the other hand, the cis-PdCl2 complex of [P(Ph)CH2N(Bz)CH2]2 is found to retain a highly flattened crown ligand conformation. Unlike the related eight-membered heterocycle 1,3,5,7-tetraoxa-2,4,6,8-tetraphosphacyclooctane which behaves as a tetradentate ligand chelating homo- or hetero-bimetallics, coordination to a second metal by these complexes was not realized.