22800-68-6

Upstream product

• 126245-48-5 (2-benzyl-2-cyano-3-phenyl-propionyl)-urea 
• 141-52-6 sodium ethanolate 
• 100-44-7 benzyl chloride 
• 105-56-6 ethyl 2-cyanoacetate 
• 107-91-5 cyanoacetic acid amide 
• 64-17-5 ethanol 
• 3779-31-5 2,2-dibenzylmalononitrile 
• 73062-47-2 ethyl 2-benzyl-2-cyano-3-phenylpropionate 
• 77526-59-1 C₃₅H₂₉AsN₂O 

Downstream Products

• 3779-31-5 2,2-dibenzylmalononitrile 
• 93649-25-3 dibenzyl-malonic acid diamide 

Relevant academic research and scientific papers

A facile and versatile electro-reductive system for hydrodefunctionalization under ambient conditions

A general electrochemical system for reductive hydrodefunctionalization is described, employing the inexpensive and easily available triethylamine (Et3N) as a sacrificial reductant. This protocol is characterized by facile operation, sustainable conditions, and exceptionally wide substrate scope covering the cleavage of C-halogen, N-S, N-C, O-S, O-C, C-C and C-N bonds. Notably, the selectivity and capability of reduction can be conveniently switched by simple incorporation or removal of an alcohol as a co-solvent.

Homogeneous and stereoselective copper(II)-catalyzed monohydration of methylenemalononitriles to 2-cyanoacrylamides

A facile and efficient route for the homogeneous and highly stereoselective monohydration of substituted methylenemalononitriles to (E)-2-cyanoacrylamides catalyzed by copper(II) acetate monohydrate in acetic acid containing 2% water is described, and a mechanism is proposed. The protocol has proved to be suitable for the monohydration of dicyanobenzenes and 2-substituted malononitriles.