228259-91-4

Basic information

• Product Name: (Z)-1-[2-(tri-p-tolylstannyl)vinyl]-1-cyclopentanol
• CAS NO: 228259-91-4
• Molecular Weight: 503.271
• Mol File: 228259-91-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-1-[2-(tri-p-tolylstannyl)vinyl]-1-cyclopentanol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-[2-(tri-p-tolylstannyl)vinyl]-1-cyclopentanol(228259-91-4)
• EPA Substance Registry System: (Z)-1-[2-(tri-p-tolylstannyl)vinyl]-1-cyclopentanol(228259-91-4)

Safety Data

• Hazardous Substances Data: 228259-91-4(Hazardous Substances Data)

Upstream product

• 796-14-5 tri(p-tolyl)tin hydride 
• 17356-19-3 1-ethynylcyclopentanol 

Downstream Products

• 211819-36-2 (Z)-1-[2-(diiodo-p-tolylstannyl)vinyl]-1-cyclopentanol 
• 211819-30-6 (Z)-1-[2-(iododi-p-tolylstannyl)vinyl]-1-cyclopentanol 
• 211819-32-8 (Z)-1-[2-(dichloro-p-tolylstannyl)vinyl]-1-cyclopentanol 
• 211819-27-1 (Z)-1-[2-(chlorodi-p-tolylstannyl)vinyl]-1-cyclopentanol 
• 211819-29-3 (Z)-1-[2-(bromodi-p-tolylstannyl)vinyl]-1-cyclopentanol 
• 211819-34-0 (Z)-1-[2-(dibromo-p-tolylstannyl)vinyl]-1-cyclopentanol 

Relevant articles and documents

Synthesis, characterization and biological activity of (Z)-1-[2]-1-cyclopentanol and their arylhalostannyl derivatives

The synthesis and characterization by elemental analysis, IR and 1H NMR of (Z)-1 - 1-cyclopentanol,CH2(CH2)3C(OH)CHCHSnPh 3 (1) and (Z)-1 - 1-cyclopentanol, CH2(CH2)3C(OH)CHCHSn(p-toly)3 (2) are described, together with their halodemetallation by I2, Br2 and ICl to yield derivatives of the types CH2(CH2)3C(OH)CHCHSnAr3-nX n (Ar = phenyl or p-tolyl ; n = 1, 2 ; X = I, Br, Cl). The solid-state structures of two compounds have been determined by X-ray diffraction analysis. In the crystal of CH2(CH2)3C(OH)CHCHSnph3 (1) the Sn atom has a distorted tetrahedral geometry but intramolecular contact with the hydroxyl O atom has not been found. A trigonal bipyramidal geometry is found in CH2(CH2)3CC(OH)CHCH SnphBr2(11), in which OSn - interaction is noted [2.446(8) A] The biological activity of the title complexes is also investigated.