228396-55-2

Upstream product

• 152390-96-0 (Z)-N-(4-O-benzyl-1-deoxy-2,3-O-isopropylidene-L-ylidene)benzylamine-N-oxide 
• 38769-92-5 4-methoxybenzylmagnesium chloride 
• 478623-18-6 ethyl (2R,3S,4R)-4-(tert-butoxycarbonyl)amino-2,3-dihydroxy-5-(4-methoxyphenyl)pentanoate 
• 478623-17-5 ethyl (2E,4R)-4-(tert-butoxycarbonyl)amino-5-(4-methoxyphenyl)pent-2-enoate 
• 120349-75-9 (2R)-2-(tert-butoxycarbonyl)amino-3-(4-methoxyphenyl)propan-1-ol 
• 139183-60-1 [(R)-1-Formyl-2-(4-methoxy-phenyl)-ethyl]-carbamic acid tert-butyl ester 
• 94790-24-6 (2R)-tert-butoxycarbonylamino-3-(4-methoxyphenyl)propionic acid methyl ester 
• 478623-19-7 ethyl (1R,4R,5R)-5-[1-(tert-butoxycarbonyl)amino-2-(4-methoxyphenyl)ethyl]-2,2-dimethyl-1,3-dioxolane-4-carboxylate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 228396-51-8 {(1R)-1-(N-benzyl-N-hydroxyamino)-1-deoxy-1-(p-methoxybenzyl)-4-O-benzyl-2,3-O-isopropylidene-L-threitol} 

Downstream Products

• 478623-20-0 (1R,4R,5R)-1-[N-(tert-butoxycarbonyl)]-1-(5-bromomethyl-2,2-dimethyl-1,3-dioxolan-4-yl)-2-(4-methoxyphenyl)ethan-1-amine 
• 27958-06-1 (2R,3S,4S)-3,4-dihydroxy-2-(4-methoxybenzyl)pyrrolidine 
• 228396-56-3 {(1R)-1-(N-tert-butoxycarbonylamino)-1-deoxy-1-(p-methoxybenzyl)-2,3-O-isopropylidene-4-chloro-L-threitol} 

Relevant academic research and scientific papers

An efficient synthesis of (-)-deacetylanisomycin starting from D-tyrosine1

The antibiotic (-)-deacetylanisomycin was synthesized starting from D-tyrosine using Sharpless asymmetric dihydroxylation as a key reaction.

A novel, concise and highly efficient stereospecific synthesis of deacetylanisomycin

A practical and highly stereospecific synthesis of deacetylanisomycin has been achieved via the addition of p-methoxybenzylmagnesiumchloride to (Z)-N-(4-O-benzyl- 1-deoxy-2,3-O-isopropylidene-L-yliden)benzyl amine-N- oxide in an efficient manner.