228563-08-4

Upstream product

• 228421-10-1 cis-[(η(5)-(1-phenylborole)Fe(CO)2(μ-CN))2Pt(PEt3)2] 
• 103652-93-3 tricarbonyl(η5-1-phenylborole)iron 
• 14177-93-6 trans-platinum(triethylphosphine)₂(chloro)₂ 

Downstream Products

• 228421-09-8 trans-[(η(5)-(1-phenylborole)Fe(CO)2(μ-CN))2Pt(PEt3)2] 
• 228563-08-4 trans-[(η(5)-(1-phenylborole)Fe(CO)2(μ-NC))2Pt(PEt3)2] 
• 228421-11-2 ((C₄H₄BC₆H₅)Fe(CO)2CN)((C₄H₄BC₆H₅)Fe(CO)2NC)Pt(P(C₂H₅)3)2 

Relevant academic research and scientific papers

Cyano-bridged Fe-CN-Pt-NC-Fe chain complexes: Structural and spectroscopic characterization of four isomers of [{η5-(1-phenylborole)Fe(CO)2(μ-CN)} 2Pt(PEt3)2]

The cyanometalate [η5-(1-phenylborole)Fe(CO)2CN]- is used as a building block for the synthesis of heterometallic complexes. It reacts with platinum(II) precursors with formation of cyanide-bridged Fe/Pt complexes and various isomeric structures are observed depending upon the orientation of the CN ligand (linkage isomers Fe-(μ-CN)-Pt or Fe-(μ-NC)-Pt) and the cis or trans geometry around the platinum centre. Complex 7 with a Fe-(μ-NC)-Pt-(μ-CN)-Fe chain was obtained from the reaction of trans-[Pt(CN)2(PEt3)2] with [η5-(1-phenylborole)Fe(CO)2(OEt2)]. The crystal structure of cis-[{η5-(1-phenylborole)Fe(CO)2(μ-CN)} 2Pt(PEt3)2] (2) which contains a Fe-(μ-CN)-Pt-(μ-NC)-Fe chain has been determined by X-ray diffraction.