2287-57-2

Basic information

• Product Name: methyl norbornane-1-carboxylate
• Synonyms: methyl norbornane-1-carboxylate
• CAS NO: 2287-57-2
• Molecular Formula: C9H14O2
• Molecular Weight: 0
• Mol File: 2287-57-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 190.4°Cat760mmHg
• Flash Point: 63.5°C
• Appearance: /
• Density: 1.12g/cm³
• Vapor Pressure: 0.541mmHg at 25°C
• Refractive Index: 1.51
• CAS DataBase Reference: methyl norbornane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl norbornane-1-carboxylate(2287-57-2)
• EPA Substance Registry System: methyl norbornane-1-carboxylate(2287-57-2)

Safety Data

• Hazardous Substances Data: 2287-57-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H14O2/c1-11-8(10)9-4-2-7(6-9)3-5-9/h7H,2-6H2,1H3

Upstream product

• 186581-53-3 diazomethane 
• 18720-30-4 norbornane-1-carboxylic acid 
• 123463-12-7 methyl 4-iodobicyclo<2.2.1>heptane-1-carboxylate 
• 934-28-1 norbornane-2-carboxylic acid 
• 41798-00-9 acide bicyclo<2.2.1>heptane peroxycarboxylique-1 
• 74830-47-0 exo,endo-2-bromobicyclo<2.2.1>heptane-1-carboxylic acid 
• 2534-90-9 exo-2-bromobicyclo<2.2.1>heptane-1-carboxylic acid 
• 85173-54-2 exo-2-bromobicyclo<2.2.1>heptane-1-carboxylic acid chloride 
• 15448-77-8 4-carbomethoxybicyclo<2.2.1>heptane-1-carboxylic acid 
• 15023-45-7 methyl exo-2-bromobicyclo<2.2.1>heptane-1-carboxylate 

Downstream Products

• 94710-41-5 Phenylcarbamoryl-Derivat d. Dimethyl-norbornyl-⁽¹⁾-carbinols 
• 149891-94-1 bicyclo<2.2.2>octane-1-carboxaldehyde-d tosylhydrazone 
• 7363-97-5 bicyclo<2.2.2>octane-1-carboxaldehyde tosylhydrazone 
• 2574-42-7 bicyclo<2.2.2>octane-1-methanol 
• 699-55-8 bicyclo[2.2.2]octane-1-carboxylic acid 
• 18720-30-4 norbornane-1-carboxylic acid 

Relevant articles and documents

Protected amino hydroxy adamantane carboxylic acid and process for its preparation

Dipeptidyl peptidase IV (DP 4) inhibiting compounds are provided. The provided compounds can be used for treating diabetes and related diseases, especially Type II diabetes, and other diseases as set out herein, employing such DP 4 inhibitor or a combination of such DP 4 inhibitor and one or more of another antidiabetic agent such as metformin, glyburide, troglitazone, pioglitazone, rosiglitazone and/or insulin and/or one or more of a hypolipidemic agent and/or anti-obesity agent and/or other therapeutic agent.

Bicyclonon-1-ene: Matrix Isolation and Spectroscopic Characterization of a Moderately Strained Bridgehead Olefin

Bicyclonon-1-ene was generated in low-temperature matrices and in fluid solutions by photodecomposition of bicyclooct-1-yldiazomethane and its photorearrangement product, 3-(bicyclooct-1-yl)diazirine.It was characterized by IR and UV absorption and by 1H and 13C NMR spectroscopy.Further evidence for the proposed structure was provided by self-trapping and by the spectral effects of deuteration on the olefinic carbon.Observed IR spectra and isotopic shifts agree well with the results of semiempirical (MNDO) and ab initio (SCF/6-31G*) calculations.

ETUDE DU CARACTERE NUCLEOPHILE DES RADICAUX LORS DE LA REACTION DE TRANSFERT SUR LA LIAISON O-O DES PERACIDES

Peracids RCO3H yield free radicals R. which react either with the peracid or with solvent giving the alcohol ROH and the hydrocarbon RH.The nucleophilic character of the free radicals was modified either by substitution of the carbon bearing the odd electron by inductive groups or by changing the free radical hybridation by the means of blocked structures such as cyclic or bicyclic free radicals.For each R., the measurement of the ratio ROH/RH establishes a reactivity scale for R. with the peracid O-O bond.This reactivity does not depend on free radical stability but depends strongly on nucleophilic character.A primary free radical is less reactive than a secondary one, and is much less reactive than a tertiary one.A bridgehead free radical as the bicycloheptyle-1 does not react with the peracid.These results are interpreted to indicate a transition state with charge transfer (polar effect), the peracid being electrophilic and the free radical nucleophilic; PMO theory is discussed.