2291-82-9Relevant academic research and scientific papers
Synthesis of alkoxystannanes by reactions of O-(organylstannyl) carbamates with alcohols
Komarov,Ryzhkova,Andreev
, p. 936 - 938 (2007/10/03)
Reactions of O-(organylstannyl) carbamates with alcohols afford alkoxystannanes and proceed most completely on heating in an excess of alcohol. The reactions provide a new approach to the synthesis of difficultly accessible alkoxystannanes.
A facile synthesis of 1-halo- and 1-organoxygermatranes
Nasim, Mohammed,Livantsova, L. I.,Zaitseva, G. S.,Lorberth, J.
, p. 85 - 91 (2007/10/02)
Interaction of the readily available 1-trimethylsiloxygermatranes (1a, 1b) with various halogenating reagents (Me3SiBr, Me3SiI, HF and SOCl2) has given the 1-halogermatranes (2a-2f).The 1-halogermatranes (2a, 2b) have been converted into the corresponding 1-organoxygermatranes by treatment with trialkylalkoxystannanes (3a-3f).The corresponding 1-organoxygermatranes (4d, 4e, 4f) were made by interaction of 1-hydroxygermatrane monohydrate with the corresponding hydroxy derivatives).
