22920-33-8

Basic information

• Product Name: Naphthalene, 1-[(1E)-2-(4-chlorophenyl)ethenyl]-
• CAS NO: 22920-33-8
• Molecular Formula: C18H13Cl
• Molecular Weight: 264.754
• Mol File: 22920-33-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Naphthalene, 1-[(1E)-2-(4-chlorophenyl)ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 1-[(1E)-2-(4-chlorophenyl)ethenyl]-(22920-33-8)
• EPA Substance Registry System: Naphthalene, 1-[(1E)-2-(4-chlorophenyl)ethenyl]-(22920-33-8)

Safety Data

• Hazardous Substances Data: 22920-33-8(Hazardous Substances Data)

Upstream product

• 90-14-2 1-Iodonaphthalene 
• 132536-25-5 4-chlorostyryltrimethylsilane 
• 637-87-6 1-Chloro-4-iodobenzene 
• 1073-67-2 4-vinylbenzyl chloride 
• 85-46-1 1-Naphthalenesulfonyl chloride 
• 51044-12-3 (4-chlorobenzyl)triphenylphosphonium bromide 
• 66-77-3 1-naphthaldehyde 

Downstream Products

• 132334-12-4 cis-1-(4-chlorophenyl)-2-(1-naphthyl)ethene 

Relevant articles and documents

One-pot palladium-catalyzed highly chemo-, regio-, and stereoselective synthesis of trans-stilbene derivatives. A concise and convenient synthesis of resveratrol

A convenient, efficient and highly chemo-, regio-, and stereoselective one-flask synthetic method is reported for the construction of unsymmetrical (or symmetrical) trans-stilbene derivatives based on two sequential Heck-type reactions using tetraalkylammonium salt-based catalyst systems and vinyltrimethylsilane as double bond equivalents. Resveratrol has thus been concisely synthesized.

Palladium-catalyzed desulfitative mizoroki-heck couplings of sulfonyl chlorides with mono-and disubstituted olefins: Rhodium-catalyzed desulfitative heck-type reactions under phosphine- And base-free conditions

New conditions have been found for the desulfitative Mizoroki-Heck arylation and trifluoromethylation of mono- and disubustituted olefins with arenesulfonyl and trifluoro-methanesulfonyl chlorides. Thus (E)-1,2- disubstituted alkenes with high ster-eoselectivity and 1,1,2-disubstituted alkenes with 12:1 to 21:1 E/Z steroselectivity can be obtained. Herrmann's palladacycle at 0.1 mol% is sufficient to catalyze these reactions, for which electron-rich or electron-poor sulfonyl chlorides and alkenes are suitable. If phosphine- and base-free conditions are required. 1 mol% [RriCl(C 2,H4)2] catalyzes the desulfitative cross-cou pling reactions. Contrary to results reported for [RuCl2(PPh 3)2]-catalyzed coupling reactions with sulfonyl chlorides, the palladium and rhodium desulfitative Mizoroki-Heck coupling reactions are not inhibited by radical scavenging agents. Possible sulfones arising from the sulfonylation of alkenes at 60°C are not desulfitated at higher temperatures in the presence of the Pd or Rh catalysts.