22929-53-9Relevant academic research and scientific papers
Strain-Promoted Oxidation of Methylenecyclopropane Derivatives using N-Hydroxyphthalimide and Molecular Oxygen in the Dark
Anderson, T. E.,Woerpel, K. A.
, (2020/07/30)
The hydroperoxidation of alkylidenecyclopropanes and other strained alkenes using an N-hydroxylamine and molecular oxygen occurred in the absence of catalyst, initiator, or light. The oxidation reaction proceeds through a radical pathway that is initiated by autoxidation of the alkene substrate. The hydroperoxides were converted to their corresponding alcohols and ketones under mild conditions.
The chemistry of small-ring compounds. Part 47. Small-ring interference in the ozonolysis of cyclopropylidenecycloalkanes
Heuvel, C. J. M. van den,Hofland, A.,Velzen, J. C. van,Steinberg, H.,Boer, Th. J. de
, p. 233 - 240 (2007/10/02)
Ozonolysis of olefins Ia-c containing a cyclpropylidene group, does not follow the classical Criegee mechanism but gives the anomalous products IIa-c, IIIa-c, IVa-c, and Va-c, as outlined in Scheme 2.None of these oxidation products contains the cycloprop
