2302-70-7Relevant academic research and scientific papers
Gold phosphole complexes as efficient catalysts for alkyne activation
Fourmy, Kevin,Mallet-Ladeira, Sonia,Dechy-Cabaret, Odile,Gouygou, Maryse
supporting information, p. 1571 - 1574 (2013/05/08)
Gold(I) complexes bearing monophosphole ligands were synthesized, and their electronic and steric properties were compared to those of their triphenylphosphine-based counterparts. Cationic phosphole-based gold(I) complexes are active and selective in enyne cycloisomerization and in olefin cyclopropanation, with a good correlation between the ligand σ-donor ability and the catalytic activity. For the most efficient ligand, 1-phenyl-2,3,4,5-tetramethylphosphole (TMP), a highly active, selective, and stable cationic [Au(TMP)(CH3CN)]SbF6 complex was isolated.
SYNTHESIS AND PHOTOCHEMICAL REACTION OF DIELS-ALDER ADDUCT OF PHOSPHOLE OXIDE AND CYCLOPENTADIENE
Tomioka, Hideo,Miura, Shinichi,Izawa, Yasuji
, p. 3353 - 3356 (2007/10/02)
Irradiation of 1-phenylphosphole oxide-cyclopentadiene adduct gave a caged product, whereas similar irradiation of 1,2,5-triphenylphosphole oxide-cyclopentadiene adduct afforded a cleavaged product.
