23038-14-4Relevant academic research and scientific papers
1,2-diastereoselection induced by chiral silicon in the addition of Grignard reagents to acylsilanes
Bonini, Bianca F.,Masiero, Stefano,Mazzanti, Germana,Zani, Paolo
, p. 6801 - 6804 (2007/10/02)
The reaction of acylsilanes 1 with Grignard reagents gives the diastereomeric α-hydroxysilanes 3. The level of asymmetric induction depends on the nature of R1 and R2. Good results were obtained for R1=t-Bu, R2=
