111916-80-4Relevant academic research and scientific papers
Preparation of optically active n-butyl(methyl)phenyl-, tert- butyl(methyl)phenyl- and isopropyl(methyl)phenylsilanes from the corresponding silyl chlorides using 2,2'-dihydroxy-1,1'-binaphthyls as resolving agents
Jankowski, Pawel,Schaumann, Ernst,Wicha, Jerzy,Zarecki, Andrzej,Adiwidjaja, Gunadi,Asztemborska, Monika
, p. 1029 - 1030 (2000)
Enantiomeric silanes 4a, 4b and 4c were obtained from the corresponding racemic silyl chlorides via diastereomeric derivatives with (R)- [1,1']binaphthalenyl-2,2'-diol; the optical purity of silanes 4a and 4c was determined (> 98% ee) by HPLC using a chir
Stereospecific formation of optically active trialkylsilyllithiums and their configurational stability
Omote, Masakatsu,Tokita, Tetsushi,Shimizu, Yasutaka,Imae, Ichiro,Shirakawa, Eiji,Kawakami, Yusuke
, p. 20 - 25 (2007/10/03)
Optically active trialkylsilyllithiums, (R)-(n-butyl)methylphenylsilyllithium (63% ee) and (S)-methyl(1-naphthyl)phenylsilyllithium (96% ee), were prepared by cleavage of the silicon-silicon bond of (R)-1-(n-butyl)-1 -methyl-1-phenyl-2,2-diphenyl-2-methyl
