23040-17-7Relevant academic research and scientific papers
STUDIES ON THE MECHANISM OF ACETOLYSIS OF DIPHENYLPHOSPHINYLPHENYLDIAZOMETHANE
Yoshifuji, Masaaki,Choi, Yoon Jung,Inamoto, Naoki
, p. 3 - 8 (2007/10/02)
In an attempt to prove the existence of an oxaphosphorirane intermediate during the acetolysis reaction of diphenylphosphinylphenyldiazomethane (1), 1 was decomposed in 18O-labeled acetic acid.However, the spectral analyses of the phosphinyl acetate (7d) thus obtained indicated that 1,2-oxygen migration caused by the formation of the anticipated oxaphosphorirane seemed not to occur.
ORGANISCHE PHOTOCHEMIE XXXII Beitrag ueber Photoreaktionen von Aroyl-diphenylphosphinen in Loesung
Dankowski, Manfred,Praefcke, Klaus
, p. 105 - 108 (2007/10/02)
Three new examples to photoreactions of aroyl diphenyl phosphines which undergo α-cleavage as well as 1,2-oxygen transfer from the carbonyl group onto the phosphorous atom are described.Both reactions also occur in the mass spectrometer.
