23080-23-1

Basic information

• Product Name: 1-(4-CHLORO-PHENYL)-2-[2-(4-CHLORO-PHENYL)-2-OXO-ETHYLSULFANYL]-ETHANONE
• Synonyms: 1-(4-CHLORO-PHENYL)-2-[2-(4-CHLORO-PHENYL)-2-OXO-ETHYLSULFANYL]-ETHANONE
• CAS NO: 23080-23-1
• Molecular Formula: C₁₆H₁₂Cl₂O₂S
• Molecular Weight: 339.24
• Mol File: 23080-23-1.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-(4-CHLORO-PHENYL)-2-[2-(4-CHLORO-PHENYL)-2-OXO-ETHYLSULFANYL]-ETHANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-CHLORO-PHENYL)-2-[2-(4-CHLORO-PHENYL)-2-OXO-ETHYLSULFANYL]-ETHANONE(23080-23-1)
• EPA Substance Registry System: 1-(4-CHLORO-PHENYL)-2-[2-(4-CHLORO-PHENYL)-2-OXO-ETHYLSULFANYL]-ETHANONE(23080-23-1)

Safety Data

• Hazardous Substances Data: 23080-23-1(Hazardous Substances Data)

Upstream product

• 536-38-9 4-chlorobenzoylmethyl bromide 
• 64-17-5 ethanol 
• 937-20-2 p-chlorophenacyl chloride 
• 99-91-2 para-chloroacetophenone 
• 25917-49-1 1-(4-chlorophenyl)-2-(p-tolylsulfonyloxy)ethanone 
• 108-90-7 chlorobenzene 

Downstream Products

• 65263-10-7 3,6-bis(4-chlorophenyl)-2,7-dihydro-1,4,5-thiadiazepine 
• 19221-13-7 3,5-Bis-4-chlorophenyl-2H-1,4-thiazine 
• 138711-18-9 1-(4-Chloro-phenyl)-2-[2-(4-chloro-phenyl)-2-oxo-ethanesulfinyl]-ethanone 
• 139961-26-5 2,6-Di(4-chlorobenzoyl)-3,5-di(4-methylphenyl)tetrahydro-1,4-thiazine 
• 1393811-91-0 cis-2,6-di(4-chlorophenyl)-1,4-oxathiane 
• 205527-20-4 1-(4-Chloro-phenyl)-2-[2-(4-chloro-phenyl)-2-hydroxy-ethylsulfanyl]-ethanol 
• 1391976-29-6 bis(4-chlorophenylethynyl) sulfide 
• 1159998-83-0 [3-(4-chlorophenyl)thiophene-2,5-diyl]bis[(4-chlorophenyl)methanone] 
• 7099-88-9 4-chlorophenylglyoxylic acid 
• 1428263-67-5 1-(4-chlorophenyl)-2-tetrahydro-1H-1-pyrrolyl-2-thioxo-1-ethanone 
• 128592-66-5 1-(4-chlorophenyl)-2-(piperidin-1-yl)-2-thioxoethan-1-one 
• 1400898-60-3 1-(4-chlorophenyl)-3-(4-methylphenyl)-5-phenyl-1,5-pentanedione 
• 1400898-58-9 1-(4-chlorophenyl)-3,5-diphenyl-1,5-pentanedione 
• 1400898-63-6 1,3-di(4-chlorophenyl)-5-(4-methylphenyl)-1,5-pentanedione 

Relevant articles and documents

One-pot preparation of arylethynyl sulfides and bis(arylethynyl) sulfides

An efficient preparation for arylethynyl sulfides 1 and bis(arylethynyl) sulfides 2 has been accomplished through a one-pot, three-step strategy that starts from arylethanonyl sulfides and bis(arylethanonyl) sulfides, respectively, without the use of various terminal arylacetylenes as substrates. When lithium hexamethyldisilazane (LHMDS), ClP(O)(OEt)2, and LHMDS were sequentially added to a tetrahydrofuran solution of different substrates [arylethanonyl sulfides or bis(arylethanonyl) sulfides], 1 or 2 were obtained in moderate to good yields. The reaction procedure involves the formation of an enol phosphate and a subsequent base-induced elimination. An efficient preparation of arylethynyl sulfides 1 and bis(arylethynyl) sulfides 2 has been accomplished by a one-pot, three-step strategy that starts from arylethanonyl sulfides and bis(arylethanonyl) sulfides, respectively, to give 1 and 2 in moderate to good yields. The reaction mechanism involves the formation of an enol phosphate that undergoes a subsequent base-induced elimination. Copyright

Synthesis of oxathiane and morpholine from acyclic precursors: A modified Mitsunobu reaction

Synthesis of a set of isomeric 2,4,6-triarylmorpholines and 2,6-diaryloxathianes from the corresponding 1,5-diols has been described. The method provides an efficient route to six-membered heterocycles from acyclic diols and is found to be better than Mitsunobu procedure in yield and waste management. In a related study, the ring contraction of pyranone to two isomeric cyclopentenone derivatives through Nazarov reaction has been noticed.

Convenient synthesis of symmetrical diketosulfides from enolizable ketones using [hydroxy(tosyloxy)iodo]benzene and Na2S·9H20

An efficient method for the preparation of symmetrical diketosulfides of the type ArCOCH2SCH2COAr has been developed from the reaction of [hydroxy(tosyloxy)iodo]benzene with various acetophenones, followed by treatment with Na2