23086-31-9Relevant academic research and scientific papers
BF3-Assisted Reactions of 1-Benzothiophen-3(2H)-one with Various Ketones: a Convenient Entry to 2-Methylene-1-benzothiophen-3(2H)-one and/or 6H-Di[1]benzothieno[3,2-b:2,3-e]pyran Derivatives
Fraleoni, Alessandro,Zanirato, Paolo
, p. 2401 - 2420 (2007/10/03)
The title compounds were obtained by BF3-assisted reactions of 1-benzothiophen-3(2H)-one with nine ketones in diethyl ether at room temperature in moderate to high yields. The pyran 1 and ylidene 2 ratios prove to be dependent upon electronic and steric f
Conversions of Thiochroman-4-ones into 1,2-Benzothiazepine, Benzothiophen, and 1,2-Benzisothiazole Systems via Sulphimide Intermediates
Tamura, Yasumitsu,Takebe, Yasushi,Bayomi, Said Mohamad M.,Mukai, Chisato,Masazumi, Ikeda,et al.
, p. 1037 - 1040 (2007/10/02)
Reaction of thiochroman-4-ones (1a-g) with chloramine-T gave the corresponding N-tosylsulphimides (2a-g) and sulphoxides (5a-g).The N-tosylsulphimides (2a-d), on reaction with triethylamine in chloroform, gave 2-tosyl-2,3-dihydro-1,2-benzothiazepin-5(4H)-
