23094-29-3Relevant academic research and scientific papers
Correlation of the rates of solvolysis of 3,4,5-trimethoxy- and 2,4,6-trichlorobenzoyl chlorides
Park, Kyoung-Ho,Kevill, Dennis N.
, p. 647 - 653,7 (2020/07/30)
The introduction of methoxy groups into the 3- and 5-positions of 4-methoxybenzoyl chloride leads to a reduction in specific rates of solvolysis. An extended Grunwald-Winstein equation correlation for the specific rates of solvolysis of 3,4,5-trimethoxybenzoyl chloride gives sensitivities towards changes in solvent nucleophilicity (l value) of 0.29 and towards changes in solvent ionising power (m value) of 0.54. The low m value allows specific rates to be determined in highly ionising fluoroalcohol-H2O mixtures. A parallel correlation of the specific rates of solvolysis of 2,4,6- trichlorobenzoyl chloride reveals that solvolyses in 100% and 90% ethanol or methanol do not appreciably follow the ionisation pathway indicated for solvolyses in the other solvents and it is proposed that, despite the two ortho-substituents, the addition-elimination pathway has become dominant.
Facile oxidative conversion of alcohols to esters using molecular iodine
Mori, Naoshi,Togo, Hideo
, p. 5915 - 5925 (2007/10/03)
A simple, efficient, and high-yield procedure for the oxidative conversion of alcohols to various types of esters and ketones, with molecular iodine and potassium carbonate was successfully carried out.
Facile conversion of alcohols to the corresponding 2,2,2-trifluoroethyl esters with molecular iodine and potassium carbonate in 2,2,2-trifluoroethanol
Mori, Naoshi,Togo, Hideo
, p. 880 - 882 (2007/10/03)
A simple, effective, and high-yield procedure for the oxidative conversion of primary alcohols to the corresponding 2,2,2-trifluoroethyl esters, with molecular iodine and potassium carbonate in 2,2,2-trifluoroethanol, was studied.
