230975-17-4Relevant academic research and scientific papers
Significant zirconium-alkyl group effects on ion pair formation thermodynamics and structural reorganization dynamics in zirconocenium alkyls
Beswick, Colin L.,Marks, Tobin J.
, p. 2410 - 2412 (1999)
Substantial Zr-alkyl group (R) effects on ion pair thermodynamic stability as well as on ion pair solution structure and structural dynamics are reported in the [(1,2-Me2Cp)2ZrR]+[CH3B(C 6F5/sub
Metal-alkyl group effects on the thermodynamic stability and stereochemical mobility of B(C6F5)3-derived Zr and Hf metallocenium ion-pairs
Beswick,Marks
, p. 10358 - 10370 (2007/10/03)
This paper reports significant dependence of ion-pair formation energetics and stereomutation rates upon the metal-bound alkyl substituent (R) and the solvent dielectric constant in the metallocenium series (1,2-Me2Cp)2MR+
