23099-78-7Relevant academic research and scientific papers
Kinetics and mechanism of the reaction of 10-phenylphenothiazine dication with water in acetonitrile
Yasukouchi, Kazuo,Taniguchi, Isao,Yamaguchi, Hiroko,Ayukawa, Jiro,Ohtsuka, Koichi,Tsuruta, Yukio
, p. 1679 - 1683 (1981)
The reaction of electrogenerated 10-phenylphenothiazine (PPTZ) dication (PPTZ2+) with water was investigated in acetonitrile containing 0.5 M NaClO4 by cyclic voltammetry and controlled-potential electrolysis. The cyclic voltammogram
Catalytic oxidation of chlorpromazine and related phenothiazines. Cation radicalsas the reactive intermediates in sulfoxide formation
Bosch, Eric,Kochi, Jay K.
, p. 1057 - 1064 (2007/10/02)
The aerial oxidation of various phenothiazines to the corresponding sulfoxides is catalysed by nitric oxide and related nitrogen oxides.The reactive intermediate in the catalytic autooxidation is the phenothiazine cation radical which is subsequently tran
Selective Catalysis of Thioether Oxidations with Dioxygen. Critical Role of Nitrosonium EDA Complexes in the Thermal and Photochemical Transfer of Oxygen Atom from Nitrogen Oxides to Sulfur Centers
Bosch, Eric,Kochi, Jay K.
, p. 3172 - 3183 (2007/10/02)
Various alkyl and aryl thioethers (R2S) are readily converted in high yields to sulfoxides in the presence of dioxygen and catalytic amounts of nitrogen dioxide.Separate experiments with stoichiometric amounts of reagents (under anaerobic conditions) esta
