7152-42-3

Basic information

• Product Name: 10-Phenyl-10H-phenothiazine
• Synonyms: 10-Phenyl-10H-phenothiazine;10-Phenylphenothiazine
• CAS NO: 7152-42-3
• Molecular Formula: C₁₈H₁₃NS
• Molecular Weight: 275.37
• Mol File: 7152-42-3.mol
• Article Data: 53

Chemical Properties

• Melting Point: 94 °C
• Boiling Point: 411.2°C at 760 mmHg
• Flash Point: 202.5°C
• Appearance: /
• Density: 1.247g/cm³
• Vapor Pressure: 5.67E-07mmHg at 25°C
• Refractive Index: 1.7
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: soluble in Acetone
• PKA: -3.48±0.20(Predicted)
• CAS DataBase Reference: 10-Phenyl-10H-phenothiazine(CAS DataBase Reference)
• NIST Chemistry Reference: 10-Phenyl-10H-phenothiazine(7152-42-3)
• EPA Substance Registry System: 10-Phenyl-10H-phenothiazine(7152-42-3)

Safety Data

• Hazardous Substances Data: 7152-42-3(Hazardous Substances Data)

Usage

Chemical Properties

light yellow powder

Uses

An organic photo-catalyst used in synthesis of small molecules as well as polymerization reactions.

InChI:InChI=1/C18H13NS/c1-2-8-14(9-3-1)19-15-10-4-6-12-17(15)20-18-13-7-5-11-16(18)19/h1-13H

Upstream product

• 92-84-2 10H-phenothiazine 
• 591-50-4 iodobenzene 
• 98546-66-8 2-ethanesulfonylmethyl-5-bromo-thiophene 
• 21848-84-0 1-bromo-2-[(2-bromophenyl)thio]benzene 
• 62-53-3 aniline 
• 583-55-1 1-Bromo-2-iodobenzene 
• 6320-02-1 o-bromothiophenol 
• 98-80-6 phenylboronic acid 
• 637-88-7 1,4-Cyclohexanedione 
• 52156-15-7 10-phenylphenothiazinium perchlorate 
• 66003-78-9 triphenylsulfonium trifluoromethanesulfonate 
• 12775-96-1 copper 
• 108-86-1 bromobenzene 
• 108-94-1 cyclohexanone 

Downstream Products

• 55267-55-5 10-phenyl-5-propylimino-5,10-dihydro-5λ⁴-phenothiazine 
• 55222-74-7 5-cyclohexylimino-10-phenyl-5,10-dihydro-5λ⁴-phenothiazine 
• 55222-72-5 5-ethylimino-10-phenyl-5,10-dihydro-5λ⁴-phenothiazine 
• 55222-70-3 5-methylimino-10-phenyl-5,10-dihydro-5λ⁴-phenothiazine 
• 55223-14-8 5-benzylimino-10-phenyl-5,10-dihydro-5λ⁴-phenothiazine 
• 23099-78-7 10-phenyl-10H-phenothiazine S-oxide 
• 154438-43-4 10-phenyl-phenothiazine-3-carbaldehyde 

Relevant articles and documents

Effective suppression of interfacial charge recombination by a 12-crown-4 substituent on a double-anchored organic sensitizer and rotating disk electrochemical evidence

Mono/double-anchored phenothiazine-based dyes (DCE1-DCE4) containing various N-substituents (12-crown-4-substituted phenyl, 4-hexoxyphenyl, and bare phenyl) were synthesized and applied as sensitizers for dye-sensitized solar cells (DSSCs). The incorporat

Photoredox Catalytic Activation of Sulfur Hexafluoride for Pentafluorosulfanylation of α-Methyl- and α-Phenyl Styrene

Sulfur hexafluoride is inert, non-toxic, and cannot simply be applied as pentafluorosulfanylation reagent. We present the first photoredox catalytic way to convert it into pentafluorosulfanylated α-methyl and α-phenyl styrenes simply by using light. The work tackles the challenges of precise activation of sulfur hexafluoride by a photoredox catalyst with designed consecutive electron transfer cycles in a fashion that styrenes trap the generated pentafluorosulfanyl radical. The method overcomes the highly problematic access to vinylic and allylic pentafluorosulfanyl styrenes and combines it with the disposal of the most potent greenhouse gas. Together with the use of light as energy source, an exceptionally high level of sustainability is gained.

Photoredox Catalytic α-Alkoxypentafluorosulfanylation of α-Methyl- and α-Phenylstyrene Using SF6

SF6 was applied as pentafluorosulfanylation reagent to prepare ethers with a vicinal SF5 substituent through a one-step method involving photoredox catalysis. This method shows a broad substrate scope with respect to applicable alcoh

Unveiling Potent Photooxidation Behavior of Catalytic Photoreductants

We describe a photocatalytic system that reveals latent photooxidant behavior from one of the most reducing conventional photoredox catalysts, N-phenylphenothiazine (PTH). This aerobic photochemical reaction engages difficult to oxidize feedstocks, such as benzene, in C(sp2)-N coupling reactions through direct oxidation. Mechanistic studies are consistent with activation of PTH via photooxidation and with Lewis acid cocatalysts scavenging inhibitors inextricably formed in this process.

Photoactivated novel organic small-molecular matrixes and preparation method thereof, and application of photoactivated novel organic small-molecular matrixes in MALDI mass spectrometric detection

The invention provides photoactivated novel organic small-molecular matrixes and a preparation method thereof, and application of the photoactivated novel organic small-molecular matrixes in MALDI mass spectrometric detection. According to the invention,

Light-promoted synthesis of surface-grafted polymers bearing pyridine groups by metal-free ATRP in microliter volumes

Polymers with pendant pyridine groups (PPPGs) are pH responsive weak polyelectrolytes potentially attractive for many applications such as sensors, antibacterial coatings, and ion gating systems. Synthesis of PPPGs by classical atom transfer radical polym