23120-99-2Relevant academic research and scientific papers
On the Role of the Solid-Gas Interface in the Thermolysis of Trimethylgermane and Trimethylstannane
Harrison, Philip G.,McManus, James,Podesta, David M.
, p. 291 - 293 (1992)
Metal film surfaces have a profound effect on the thermal decomposition of Me3MH (M = Ge and Sn), both of which unusually decompose by half-order kinetics at elevated temperature.
Synthesis and Properties of Trimethyl(trifluorosilyl)stannane
D'Errico, John,Sharp, Kenneth G.
, p. 1879 - 1882 (2007/10/02)
Trimethyltin hydride reacts with SiF3SiF3 or SiF3SiF2H to give the new compound SnMe3(SiF3) in 75-80 percent yield.No reaction was observed between SnMe3H and SiF3SiH3.Hydrogen-deuterium exchange was observed between tin and silicon during the course of deuterium-labelling experiments.Dimethylstannylene (SnMe2) was implicated as an intermediate by trapping experiments in the thermolysis of SnMe3(SiF3).
REACTIONS OF (CH3)3SnM(CH3)3 (M = Si; Ge) WITH CHLOROTRIMETHYLSTANNANE AND DICHLORODIMETHYLSTANNANE IN METHANOL SOLUTION
Cuthberston, Matthew J.,Wells, Peter R.
, p. 25 - 38 (2007/10/02)
The reactions of (CH3)3SnM(CH3)3 for M = Si and Ge with (CH3)3SnCl or (CH3)2SnCl2 in methanol follow the same path as the corresponding reactions of (CH3)6Sn2, and involve Sn-CH3 cleavage at essentially the same rate.Complications arise from reaction of H
