2319-40-6Relevant academic research and scientific papers
SILAETHENE II. DARSTELLUNG UND CHARAKTERISIERUNG VON 1,3-DISILACYCLOBUTANEN
Auner, N.,Grobe, J.
, p. 151 - 178 (2007/10/02)
1,3-Disilacyclobutanes of the types R1R2SiSiR1R2 are prepared (a) by ring synthesis from chloromethylchlorosilanes R1R2Si(CH2Cl)Cl, (b) by thermolysis of monosilacyclobutanes , and (c) by substitution of chlorine with alkyl groups in SiCl-containing 1,3-disilacyclobutanes, obtained by procedures (a) or (b).The compounds have been characterized by analytical and spectroscopic investigations.The synthetic methods are critically compared.
THERMOLYSE UND PHOTOLYSE EINIGER SILA- UND DISILACYCLOBUTANE
Jutzi, Peter,Langer, Peter
, p. 401 - 410 (2007/10/02)
The thermolysis of some 1,1-di- or 1,1,2-tri-substituted 1-silacyclobutanes leads to 1,3-disilacyclobutanes or to polymeric products.A possible intermediate silaalkene could not be stabilized, even in the presence of bulky substituents at the silicon atom.Photolysis of some di- or tri-substituted silacyclobutanes in methanol results in ring opening or in elimination of an alkene with further reaction of the intermediates with the solvent.Photolysis of the 1,1-diphenyl-2-methyl-1-silacyclobutane in cyclohexane leads to the 1,1,3,3-tetraphenyl-1,3-disilacyclobutane.The influence of the substituents at the silicon or the carbon atom on the reaction pathways is discussed.Photolysis opening and addition of methanol, whereas the 1,1,3,3-tetraphenyl-1,3-disilacyclobutane does not show any reaction.
