232944-62-6Relevant academic research and scientific papers
Synthetic applications of the Baylis-Hillman adducts: A simple stereoselective synthesis of (E)-3-(nitroxymethyl)alk-3-en-2-ones
Basavaiah, Deevi,Suguna Hyma, Rachakonda,Kumaragurubaran, Nagaswamy
, p. 5905 - 5907 (2000)
First simple, stereoselective synthesis of (E)-3-(nitroxymethyl)alk-3-en-2-ones from Baylis-Hillman adducts (4-hydroxy-3-methylenealkan-2-ones) is described. (C) 2000 Elsevier Science Ltd.
Facile synthesis of biarylmethanes and tetrasubstituted arenes: Via a base-mediated [3 + 3] benzannulation reaction of Morita-Baylis-Hillman adducts and unsaturated sulfones
Yadav, Deepak,Sharma, Sunil K.,Menon, Rajeev S.
, p. 4073 - 4076 (2019/04/30)
A facile DBU-mediated [3 + 3] benzannulation reaction of 1,3-bis-sulfonyl propenes and Morita-Baylis-Hillman (MBH) bromides is described. The benzannulation reaction afforded bis-sulfonyl biarylmethanes/arenes with complete regioselectivity. The products
Stereoselective transformation of Baylis-Hillman adducts into (3E)-3- (alkoxymethyl)alk-3-en-2-ones
Basavaiah, Deevi,Suguna Hyma, Rachakonda,Muthukumaran, Kannan,Kumaragurubaran, Nagaswamy
, p. 217 - 219 (2007/10/03)
The pure (3E)-3-(methoxymethyl)alk-3-en-2-ones and (3E)-3- (ethoxymethyl)alk-3-en-2-ones are formed in the acid induced reaction of 4- hydroxy-3-methylenealkan-2-ones with methanol and ethanol, respectively.
