232944-64-8

Upstream product

• 78-94-4 methyl vinyl ketone 
• 135-02-4 ortho-anisaldehyde 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 1308285-83-7 (S)-4-isorpopyl-4-((R)-1-(2-methoxyphenyl)-2-methylene-3-oxobutyl)-2-phenyloxazol-5(4H)-one 
• 1308286-03-4 tert-butyl 1-(2-methoxyphenyl)-2-methylene-3-oxobutyl carbonate 

Relevant academic research and scientific papers

Stereoselective transformation of Baylis-Hillman adducts into (3E)-3- (alkoxymethyl)alk-3-en-2-ones

The pure (3E)-3-(methoxymethyl)alk-3-en-2-ones and (3E)-3- (ethoxymethyl)alk-3-en-2-ones are formed in the acid induced reaction of 4- hydroxy-3-methylenealkan-2-ones with methanol and ethanol, respectively.

Synthetic applications of the Baylis-Hillman adducts: A simple stereoselective synthesis of (E)-3-(nitroxymethyl)alk-3-en-2-ones

First simple, stereoselective synthesis of (E)-3-(nitroxymethyl)alk-3-en-2-ones from Baylis-Hillman adducts (4-hydroxy-3-methylenealkan-2-ones) is described. (C) 2000 Elsevier Science Ltd.