233279-62-4Relevant academic research and scientific papers
Concise total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria Cunea
Che, Chao,Zhang, Zhong-Ning
, p. 2187 - 2193 (2007/10/03)
The total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria cunea, using a convergent synthetic strategy, was achieved through the regioselective coupling of the two fragments, chiral epoxy tosylate and 1,
Stereospecific syntheses of chiral epoxides bearing 1,4-diyne or 1,4-enyne unit via alkylative epoxide rearrangement
Che, Chao,Zhang, Zhongning
, p. 4499 - 4505 (2007/10/03)
Stereospecific syntheses of a series of chiral epoxides bearing the 1,4-diyne or 1,4-enyne unit were achieved through alkylative epoxide rearrangement, which proceeded in two steps: 1) coupling of epoxy tosylate with alkynyltrifluoroborate; and 2) ring-cl
A facile synthetic method for chiral 1,2-epoxides and the total synthesis of chiral pheromone epoxides
Zhang, Zhi-Bo,Wang, Zhi-Min,Wang, Yu-Xiu,Liu, Huan-Quan,Lei, Gui-Xin,Shi, Min
, p. 837 - 840 (2007/10/03)
Chiral 1,2-epoxy-3-alkanol tosylates were successfully synthesized from alkynols in three steps using the Sharpless AD reaction as a key step in good yields. Two chiral insect pheromone epoxides were smoothly obtained from the corresponding key intermediate.
Alkylative Epoxide Rearrangement. A Stereospecific Approach to Chiral Epoxide Pheromones
Bell, Thomas W.,Ciaccio, James A.
, p. 5153 - 5162 (2007/10/02)
The alkylative rearrangement of 1,2-epoxy-3-alkanol tosylates is applied to the synthesis of chiral epoxide pheromones.Attack at the terminal carbon atom of epoxy tosylates by lithioacetylenes and cyclization of the intermediate tosyloxy alcohols produces
