117286-14-3Relevant articles and documents
Concise total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria Cunea
Che, Chao,Zhang, Zhong-Ning
, p. 2187 - 2193 (2007/10/03)
The total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria cunea, using a convergent synthetic strategy, was achieved through the regioselective coupling of the two fragments, chiral epoxy tosylate and 1,
Alkylative Epoxide Rearrangement. A Stereospecific Approach to Chiral Epoxide Pheromones
Bell, Thomas W.,Ciaccio, James A.
, p. 5153 - 5162 (2007/10/02)
The alkylative rearrangement of 1,2-epoxy-3-alkanol tosylates is applied to the synthesis of chiral epoxide pheromones.Attack at the terminal carbon atom of epoxy tosylates by lithioacetylenes and cyclization of the intermediate tosyloxy alcohols produces