117286-14-3Relevant academic research and scientific papers
Concise total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria Cunea
Che, Chao,Zhang, Zhong-Ning
, p. 2187 - 2193 (2007/10/03)
The total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria cunea, using a convergent synthetic strategy, was achieved through the regioselective coupling of the two fragments, chiral epoxy tosylate and 1,
Total synthesis of enantiomers of (3Z,6Z)-cis-9,10-epoxy 1,3,6- henicosatriene - The pheromonal component of Diacrisia obliqua
Yadav,Valli, Madabhushi Y.,Prasad
, p. 7551 - 7562 (2007/10/03)
Synthesis of enantiomers of (3Z,6Z)-cis-9,10-epoxy 1,3,6- henicosatriene, the pheromonal component of Diacrisia obliqua was achieved through alkylative epoxide rearrangement and stereoselective Wittig olefination reactions as the key steps.
Alkylative Epoxide Rearrangement. A Stereospecific Approach to Chiral Epoxide Pheromones
Bell, Thomas W.,Ciaccio, James A.
, p. 5153 - 5162 (2007/10/02)
The alkylative rearrangement of 1,2-epoxy-3-alkanol tosylates is applied to the synthesis of chiral epoxide pheromones.Attack at the terminal carbon atom of epoxy tosylates by lithioacetylenes and cyclization of the intermediate tosyloxy alcohols produces
ALKYLATIVE EPOXIDE REARRANGEMENT. APPLICATION TO STEREOSELECTIVE SYNTHESIS OF CHIRAL PHEROMONE EPOXIDES.
Bell, Thomas W.,Claccio, James A.
, p. 865 - 868 (2007/10/02)
An approach is described for the stereospecific conversion of threo and erythro 1,2-epoxy-3-alkanol tosylates to cis and trans internal epoxides, respectively.The method is illustrated by the synthesis of chiral epoxides, including insect pheromones.
