23337-93-1Relevant articles and documents
Combination and Disproportionation Reactions of the Radical
Goergenyi, Miklos,Seres, Laszlo
, p. 1827 - 1830 (2007/10/02)
The radical (1) was produced in the di-tert-butyl peroxide-initiated and thermal decompositions of azoethane.Self-combination of 1 takes place almost exclusively at the carbon radical centre (1C).The disproportionation: combination ratio Δ(C2H5., 1N) ca. 0.38 (Δ = kd/kc) and the rate constant ratio kd(CH3., 1N)/kc(CH3., 1C) = 0.15 +/- 0.03.The cross-combination ratio Φ(CH3., 1C) = 1.38 +/- 0.11, which is lower than the cross-reaction ration Φ*(CH3., 1) ca. 2.5.