233758-90-2

Upstream product

• 233758-87-7 (1R,2R,3R)-2-benzoyl-3-[(R)-(2,2-dimethyl-[1,3]dioxolan-4-yl)]-cyclopropanecarboxylic acid, ethyl ester 
• 233758-88-8 (1R,2R,3R)-2-Benzoyl-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-cyclopropanecarboxylic acid 
• 233758-84-4 (R)-3-(2,2-dimethyl-[1,3]dioxolan-4-yl)-1-phenyl-prop-2E-en-1-one 
• 233758-85-5 (R)-3-(2,2-dimethyl-[1,3]dioxolan-4-yl)-1-phenyl-prop-2Z-en-1-one 
• 20913-05-7 (Benzoylmethylene)triphenylphosphorane 
• 233758-89-9 (1R,2R,3R)-2-benzoyl-3-[(R)-(2,2-dimethyl-[1,3]dioxolan-4-yl)]-cyclopropanecarboxylic acid, diethyl amide 

Downstream Products

• 233758-92-4 (1R,2R,3R)-2-[(R)-1,2-diacetoxyethyl]-3-diethylcarbamoylcyclopropane-carboxylic acid, phenyl ester 
• 233758-91-3 (1R,2R,3R)-2-benzoyl-3-[(R)-1,2-diacetoxyethyl]-cyclopropanecarboxylic acid, diethyl amide 

Relevant academic research and scientific papers

Synthesis of (2S,1'R,2'R,3'R)-2-(2',3'-dicarboxycyclopropyl)-glycine via the stereochemically controlled cyclopropanation of (S)-glyceraldehyde acetonide-derived enones

The reaction of ethyl dimethylsulfonium acetate bromide with aromatic enones 5a or 5b derived from (S)-glyceraldehyde acetonide under the action of DBU provides cyclopropanation products in excellent yield and good diastereoselectivity (10/1). High geomet

Stereochemically controlled cyclopropanation of (S)-glyceraldehyde acetonide-derived olefins. Synthesis of (2S,1′R,2′R,3′R)-2-(2′,3′-dicarboxycyclopropyl) glycine

(equation presented) The reactions of ethyl (dimethylsulfuranylidene)acetate or other related sulfonium ylides with olefins 1 derived from (S)-glyceraldehyde acetonide provide cyclopropanation products in good to excellent diastereoselectivity. On the bas