234078-00-3Relevant academic research and scientific papers
Total synthesis of optically active liverwort sesquiterpenes, trifarienols A and B, using phenylethylamine as a chiral auxiliary
Tori, Motoo,Hisazumi, Kenji,Wada, Tomonari,Sono, Masakazu,Nakashima, Katsuyuki
, p. 961 - 971 (2007/10/03)
The imine of (rac)-2,3-dimethylcyclohexanone 10a with (S)-(-)- phenylethylamine was reacted with methyl acrylate to yield methyl (1'S,6'R)- 3-(1',6'-dimethyl-2'-oxocyclohexyl)propanoate 4a in 26% (97% ee) after hydrolysis. When (2RS,3R)-2,3-dimethylcycloh
