234093-33-5Relevant academic research and scientific papers
Direct method for carbon-carbon bond formation: The functional group tolerant cobalt-catalyzed alkylation of aryl halides
Amatore, Muriel,Gosmini, Corinne
supporting information; experimental part, p. 5848 - 5852 (2010/09/03)
(Figure Presented). A new protocol for the direct cobaltcatalyzed alkylation of aryl halides has been developed that proceeds smoothly in the presence of phosphanes or bipyridines as ligands with a variety of alkyl halides, including challenging alkyl electrophiles bearing β hydrogen atoms (see scheme). Sensitive functional groups are tolerated on both coupling partners, thus, significantly extending the general scope of transition-metal-catalyzed alkylation of aryl halides.
One-pot Negishi cross-coupling reactions of in situ generated zinc reagents with aryl chlorides, bromides, and triflates
Sase, Shohei,Jaric, Milica,Metzger, Albrecht,Malakhov, Vladimir,Knochel, Paul
supporting information; experimental part, p. 7380 - 7382 (2009/05/07)
(Chemical Equation Presented) In situ generated aryl, heteroaryl, alkyl, or benzylic poly-functional zinc reagents obtained by the addition of zinc and LiCl to the corresponding organic iodides undergo smooth Pd(0)-catalyzed cross-coupling reactions with
