23431-45-0Relevant academic research and scientific papers
Palladium-Catalyzed 1,3-Difunctionalization Using Terminal Alkenes with Alkenyl Nonaflates and Aryl Boronic Acids
McCammant, Matthew S.,Shigeta, Takashi,Sigman, Matthew S.
, p. 1792 - 1795 (2016)
A Pd-catalyzed 1,3-difunctionalization of terminal alkenes using 1,1-disubstituted alkenyl nonaflates and arylboronic acid coupling partners is reported. This transformation affords allylic arene products that are difficult to selectively access using tra
Additions of Allylic Grignard Reagents to o-Allylphenol
Richey, Herman G.,Domalski, Martin S.
, p. 3780 - 3783 (2007/10/02)
Reactions of o-allylphenol (1a) with allylmagnesium chloride or bromide furnished 6-(o-hydroxyphenyl)-1-hexene (2a) and 4-methyl-5-(o-hydroxyphenyl)-1-pentene (3a), products resulting from both possible orientations of addition.A reaction of 1a and (2-methyl-2-propenyl)magnesium chloride gave only 6-(o-hydroxyphenyl)-2-methyl-1-hexene (2b).From comparisons with reactions of allylmagnesium chloride with o-allylanisole and allylbenzene, it is concluded that the metalated phenolic hydroxyl group, even though relatively remote from the double bond, assists the additions to 1a.
