23446-54-0Relevant academic research and scientific papers
Prenylation of 4-Methylphenol
Chukicheva, I. Yu.,Fedorova, I. V.,Kolegova, Т.А.,Kutchin, A. V.
, p. 335 - 340 (2020/04/27)
Abstract: Organoaluminum (aluminum phenolate and aluminum isopropylate) and acidicheterogeneous catalysts (zeolites C-10, C-100 and ZSM, clay KSF, sulfonic cationexchangers Fiban K-1 and Amberlist 36 Dry) were studied in the alkylation of4-methylphenol wi
A dehydrogenative diels-alder reaction of prenyl derivatives with 2,3-dichloro-5,6-dicyanobenzoquinone
Feng, Hong-Xia,Wang, Yuan-Yuan,Chen, Jie,Zhou, Ling
supporting information, p. 940 - 944 (2015/03/30)
An efficient dehydrogenative Diels-Alder (DHDA) reaction of prenyl derivatives with 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) has been developed under mild conditions, leading to a series of cyclohexene derivatives with good to excellent yields and excellent diastereoselectivity.
De novo synthesis of teleocidin B analogs
Pu, Jun,Deng, Kangwen,Butera, John,Chlenov, Michael,Gilbert, Adam,Kagan, Mike,Mattes, James,Resnick, Lynn
scheme or table, p. 1963 - 1972 (2010/04/29)
Teleocidin B analogs have been synthesized in 24 steps and 1.9% overall yield. The key steps include aromatic Claisen rearrangement, intramolecular Heck reaction of a tetra-substituted alkene, and ruthenium (II) catalyzed indole cyclization. Teleocidin an
Facile synthesis of 2,2-Dimethylchromans by Mo(CO)6 Catalyzed reaction of aryl prenyl ethers
Bernard, Angela M.,Cocco, Maria T.,Onnis, Valentina,Piras, Pier P.
, p. 256 - 258 (2007/10/03)
2,2-Dimethylchromans 3a-g are synthesized in good yields by a one-pot reaction of the aryl prenyl ethers 1a-g with a catalytic amount of Mo(CO)6 in refluxing toluene.
Terminal Olefin Oxidation: A Short Synthesis of Himasecolone
Trivedi, S. V.,Mamdapur, V. R.
, p. 1160 (2007/10/02)
A short synthesis of himasecolone (I) is reported. p-Cresyl prenyl ether (II) on Claisen rearrangement gives the olefinic phenol acetate (III), which on reaction with acetone in the presence of Mn(OAc)3 yields IV.Hydrolysis of IV leads to the title compou
