87315-61-5Relevant academic research and scientific papers
De novo synthesis of teleocidin B analogs
Pu, Jun,Deng, Kangwen,Butera, John,Chlenov, Michael,Gilbert, Adam,Kagan, Mike,Mattes, James,Resnick, Lynn
experimental part, p. 1963 - 1972 (2010/04/29)
Teleocidin B analogs have been synthesized in 24 steps and 1.9% overall yield. The key steps include aromatic Claisen rearrangement, intramolecular Heck reaction of a tetra-substituted alkene, and ruthenium (II) catalyzed indole cyclization. Teleocidin an
Terminal Olefin Oxidation: A Short Synthesis of Himasecolone
Trivedi, S. V.,Mamdapur, V. R.
, p. 1160 (2007/10/02)
A short synthesis of himasecolone (I) is reported. p-Cresyl prenyl ether (II) on Claisen rearrangement gives the olefinic phenol acetate (III), which on reaction with acetone in the presence of Mn(OAc)3 yields IV.Hydrolysis of IV leads to the title compou
