2348-01-8

Basic information

• Product Name: Trimethyl-((2S,3S,4S,5R,6R)-2,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yloxy)-silane
• CAS NO: 2348-01-8
• Molecular Weight: 308.447
• Mol File: 2348-01-8.mol

Chemical Properties

• CAS DataBase Reference: Trimethyl-((2S,3S,4S,5R,6R)-2,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yloxy)-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Trimethyl-((2S,3S,4S,5R,6R)-2,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yloxy)-silane(2348-01-8)
• EPA Substance Registry System: Trimethyl-((2S,3S,4S,5R,6R)-2,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran-3-yloxy)-silane(2348-01-8)

Safety Data

• Hazardous Substances Data: 2348-01-8(Hazardous Substances Data)

Upstream product

• 6150-07-8 methyl 3,4,6-tri-O-methyl-α-D-mannopyranoside 
• 25561-30-2 N,O-bis(trimethylsilyl)trifluoroacetamide 

Relevant articles and documents

SYNTHESIS AND MASS SPECTRA OF THE PARTIALLY METHYLATED AND PARTIALLY ETHYLATED ANHYDRO-D-MANNITOL ACETATES DERIVED BY REDUCTIVE CLEAVAGE OF PERMETHYLATED AND PERETHYLATED Saccharomyces cerevisiae D-MANNANS

Reductive cleavage of per-O-ethylated or per-O-methylated Saccharomyces cerevisiae D-mannans and subsequent acetylation had previously been shown to produce the expected derivatives of 1,5-anhydro-D-mannitol.Described herein is the independent synthesis of each of these derivatives, namely, 1,5-anhydro-2,3,4,6-tetra-O-methyl-, -2,3,4,6-tetra-O-ethyl-, -2-O-acetyl-3,4,6-tri-O-methyl-, -2-O-acetyl-3,4,6-tri-O-ethyl-, -3-O-acetyl-2,4,6-tri-O-methyl-, -3-O-acetyl-2,4,6-tri-O-ethyl-, -6-O-acetyl-2,3,4-tri-O-methyl-, -6-O-acetyl-2,3,4-tri-O-ethyl-, -2,6-di-O-acetyl-3,4-di-O-methyl-, -2,6-di-O-acetyl-3,4-di-O-ethyl-, -3,6-di-O-acetyl-2,4-di-O-methyl-, and -3,6-di-O-acetyl-2,4-di-O-ethyl-D-mannitol.The 1H-n.m.r. spectra, chemical-ionization (NH3) mass spectra, and electron-impact mass spectra for all of these derivatives are tabulated