235094-41-4Relevant academic research and scientific papers
Palladium-catalyzed asymmetric synthesis of 2-alkynyl oxacycles
Daniels, David S. B.,Thompson, Amber L.,Anderson, Edward A.
supporting information; scheme or table, p. 11506 - 11510 (2012/01/11)
Oxyacetylene: Unusual palladium-catalyzed cyclizations of cyclic and acyclic propargylic carbonates give 2-alkynyl oxacycles. The reactions proceed with very high stereoselectivity for both syn- and anti-disubstituted furans and pyrans, and with exceptional regioselectivity. In addition, two-directional cyclizations of bis-propargylic carbonate substrates yield bifurans with complete stereocontrol for all diastereomers.
Preparation of highly substituted tetrahydropyrans via a metal assisted dipolar cycloaddition reaction
Allart, Eric A.,Christie, Steven D. R.,Pritchard, Gareth J.,Elsegood, Mark R. J.
supporting information; experimental part, p. 7339 - 7341 (2010/06/14)
A range of highly substituted tetrahydropyrans have been prepared by reaction of a donor-acceptor cyclobutane, where the donor is a metal-alkyne complex, with an aldehyde under Lewis acid conditions.
Synthesis of alkylidenecyclopentenones and dialkylidenecyclopentenones via the coupling of propargylic alcohol and 2-alkyne-1,4-diol derivatives with cyclopropylcarbene-chromium complexes
Herndon, James W.,Zhu, Jin,Sampedro, Diego
, p. 4985 - 4993 (2007/10/03)
The coupling of propargylic alcohols and their derivatives with cyclopropylcarbene-chromium complexes has been investigated. The coupling reaction leads to alkylidenecyclopentenones or alkoxyalkyl-cyclopentenones, depending on the leaving group ability of
Synthesis of alkylidenecyclopentenones via the coupling of propargyl alcohol derivatives with cyclopropylcarbene-chromium complexes
Herndon, James W.,Zhu, Jin
, p. 15 - 18 (2008/02/09)
(equatio presented) The coupling of propargylic alcohols and their derivatives with cyclopropylcarbene-chromium complexes has been investigated. The coupling reaction leads to alkylidenecyclopentenones or alkoxyalkylcyclopentenones, depending on the leavi
