235104-95-7

Upstream product

• 25006-88-6 2-bromo-1,3-bis(bromomethyl)benzene 
• 4376-01-6 sodium diphenylphosphide 
• 1224868-04-5 2,6-bis[(boronatediphenylphosphanyl)methyl]bormobenzene 
• 603-35-0 triphenylphosphine 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 235104-97-9 2,6-bis[(diphenylthioxophosphanyl)methyl]benzenethiol 
• 615569-94-3 2,6-bis(diphenylphosphinomethyl)phenylbromonickel 
• 1542214-96-9 C₃₂H₂₇AuBrP₂⁽¹⁺⁾*Br^(1-) 
• 235104-98-0 2,6-bis[(diphenylphosphanyl)methyl]benzenethiol 

Relevant academic research and scientific papers

An EPR study of the intramolecular dynamics in o-semiquinonic nickel complexes with a diphosphorous pincer ligand

Square pyramidal o-semiquinonic nickel complexes with 2,6- bis(diphenylphosphinomethyl)phenyl have a flexible coordination sphere and exist in solution as the mixture of tautomers rapidly, according to EPR time scale, interconverting at room temperature.

Synthesis of oxygen- and sulfur-bridged dirhodium complexes and their use as catalysts in the chemoselective hydrogenation of alkenes

Oxygen-bridged and sulfur-bridged rhodium homobimetallic complexes were synthesized as air-stable crystals by using 2,6-bis(phosphanylmethyl)phenolate and -thiophenolate as the ligands, respectively. The oxygen-bridged dirhodium complex has a symmetrical structure where the carbon atom at the ipso position, oxygen, and two rhodium atoms are located in the same plane. It is thermally stable compared to the sulfur-bridged dirhodium complex and shows catalytic activity for hydrogenation of alkenes with high chemoselectivity.

Binuclear complexes with ligands based on the 2,6-bis(diphenylphosphinomethyl)benzene framework. Syntheses and crystal structures of [Ir2Cl2(μ-CO){2,6-(Ph2PH2) 2C6H3S}2

The new binucleating phosphinothiolate proligand 2,6-(Ph2PCH2)C6H4SH (L3H) was prepared from bromo-2,6-dimethylbenzene in a 4 step synthesis. Reaction with [IrCl(CO)(PPh3)2] in MeCN gave th