235104-97-9Relevant academic research and scientific papers
Synthesis of oxygen- and sulfur-bridged dirhodium complexes and their use as catalysts in the chemoselective hydrogenation of alkenes
Zhu, Chuan,Yukimura, Noriaki,Yamane, Motoki
experimental part, p. 2098 - 2103 (2010/06/19)
Oxygen-bridged and sulfur-bridged rhodium homobimetallic complexes were synthesized as air-stable crystals by using 2,6-bis(phosphanylmethyl)phenolate and -thiophenolate as the ligands, respectively. The oxygen-bridged dirhodium complex has a symmetrical structure where the carbon atom at the ipso position, oxygen, and two rhodium atoms are located in the same plane. It is thermally stable compared to the sulfur-bridged dirhodium complex and shows catalytic activity for hydrogenation of alkenes with high chemoselectivity.
Binuclear complexes with ligands based on the 2,6-bis(diphenylphosphinomethyl)benzene framework. Syntheses and crystal structures of [Ir2Cl2(μ-CO){2,6-(Ph2PH2) 2C6H3S}2
Dilworth, Jonathan R.,Zheng, Yifan,Griffiths, D. Vaughan
, p. 1877 - 1881 (2007/10/03)
The new binucleating phosphinothiolate proligand 2,6-(Ph2PCH2)C6H4SH (L3H) was prepared from bromo-2,6-dimethylbenzene in a 4 step synthesis. Reaction with [IrCl(CO)(PPh3)2] in MeCN gave th
