23556-90-3Relevant academic research and scientific papers
A facile one-pot synthesis of symmetrical and unsymmetrical acetaldehyde acetals from primary alcohols
Guy,DiPietro
, p. 687 - 692 (2007/10/02)
Initial formation of a vinyl ether 2 by treatment of a primary alcohol 1 with ethyl vinyl ether in the presence of mercury (II) acetate followed by treatment with the same or a different alcohol in the presence of p-toluenesulfonic acid affords the symmetrical and unsymmetrical acetaldehyde acetals 3 in good overall yield. The method is easily scaled up and represents a significant improvement over currently available procedures.
Chiral Recognition in the Reaction of the Enolate derived from 5-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph> with 1-Phenylethyl Bromide
Davies, Stephen G.,Middlemiss, David,Naylor, Alan,Wills, Martin
, p. 797 - 799 (2007/10/02)
Chiral recognition to the extent of 30:1 has been observed in the reaction between the homochiral iron acyl complex 5-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph) and racemic 1-phenylethyl bromide.
