23624-40-0Relevant academic research and scientific papers
Diagnosing the plasma formed during acoustic cavitation in [BEPip][NTf2] ionic liquid
Pflieger, Rachel,Lejeune, Manuel,Noel, Cédric,Belmonte, Thierry,Nikitenko, Sergey I.,Draye, Micheline
, p. 1183 - 1189 (2019)
Sonoluminescence (SL) spectra of a very dry [BEPip][NTf2] ionic liquid were measured in the first minutes of sonication under Ar. The intense sonoluminescence allowed us to monitor the time-evolution of the SL spectra. Several molecular emissions were observed. Rovibronic temperatures of C2 and CN were determined giving vibrational temperatures of 5800 ± 500 K and 6000 ± 500 K and rotational temperatures (i.e. translational or gas temperatures) of 4000 ± 500 K. These temperatures stay remarkably constant during the sonolysis, while SL spectra undergo strong changes that illustrate the very fast evolution of the plasma during the first minutes of sonication. The expected strong decrease in the plasma electron energy also reflects in the evolution of the populations of CH electronically excited states. The physical meaning of temperatures derived from molecular emissions in SL spectra is discussed.
Surface characterization of 1-butyl-1-ethylpiperidinium bromide by inverse gas chromatography
Papadopoulou, Stella K.,Papaiconomou, Nicolas,Baup, Stéphane,Iojoiu, Cristina,Svecova, Lenka,Thivel, Pierre-Xavier
, (2019)
This work addresses the surface characterization of an organic salt based on a piperidinium cation and a halide anion, similar to a first generation ionic liquid, using the Inverse Gas Chromatography (IGC)technique. IGC was employed in order to assess the dispersive surface energy and the acid/base character of 1-butyl-1-ethylpiperidinium bromide, [C2C4PIP]Br at a temperature range (313.15–343.15 K)well below its melting point, where the retention mechanism is governed by the surface adsorption of the probes. This type of characterization was possible due to the high melting point of [C2C4PIP]Br, namely 413.15 K. The dispersive component of the surface energy was estimated with the aid of the Schultz method and the Dorris-Gray method. Results obtained using the first method were higher than the ones obtained by the latter. The discrepancy between the two methods was found to increase with the increase of temperature. The acid/base characterization was implemented by using the Flour and Papirer approach as well as the Brookman and Sawyer method. The acidity and basicity constants of the surface of [C2C4PIP]Br revealed that it is amphoteric with a predominantly basic character.
