23637-57-2

Upstream product

• 54277-08-6 meso-1,4-diphenyl-but-2-yne-1,4-diol 
• 100-52-7 benzaldehyde 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 4482-17-1 1,4-diphenyl-but-2-yne-1,4-diol 
• 4482-17-1 rac-1,4-diphenylbut-2-yne-1,4-diol 
• 959-28-4 1,4-diphenylbut-2-ene-1,4-dione 

Downstream Products

• 959-27-3 (Z)-1,4-diphenylbut-2-ene-1,4-dione 
• 107538-22-7 meso-1.4-diphenyl-butene-(2t)-diol-(1.4) 

Relevant academic research and scientific papers

Unsaturated syn - And anti -1,2-amino alcohols by cyclization of allylic bis-trichloroacetimidates. Stereoselectivity dependence on substrate configuration

Disubstituted allylic bis-imidates undergo Lewis acid catalyzed or spontaneous cyclization to oxazolines, which are precursors of unsaturated amino alcohols. Stereoselectivity of the cyclization is mainly determined by the substrate configuration. Highly

Nucleophilic Attack on a Carbonyl Group Conjugated to a Chiral Centre: A Search For a Vinylogous Cram's Rule

In a search for a vinylogous version of Cram's rule, 1,4-diphenylbut-2-ene-1,4-dione (5), 4-methoxy-1,4-diphenylbut-2-en-1-one (9), and hex-3-ene-2,5-dione (13) are found to be reduced with low or negligible diastereoselectivity.Similarly, the phenyl Grignard reagent showed no diastereoselectivity in its reaction with 4-methoxy-4-phenylbut-2-enal (12)