2364-62-7

Basic information

• Product Name: butyl 2-methoxybenzoate
• CAS NO: 2364-62-7
• Molecular Formula: C₁₂H₁₆O₃
• Molecular Weight: 208.2536
• Mol File: 2364-62-7.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 292.5°C at 760 mmHg
• Flash Point: 118.3°C
• Density: 1.036g/cm³
• Vapor Pressure: 0.00183mmHg at 25°C
• Refractive Index: 1.495
• CAS DataBase Reference: butyl 2-methoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: butyl 2-methoxybenzoate(2364-62-7)
• EPA Substance Registry System: butyl 2-methoxybenzoate(2364-62-7)

Safety Data

• Hazardous Substances Data: 2364-62-7(Hazardous Substances Data)

Upstream product

• 529-28-2 4-iodoanisol 
• 71-36-3 butan-1-ol 
• 21615-34-9 2-Methoxybenzoyl chloride 
• 37170-50-6 di(methyl)tert-butyl(n-butoxy)silane 
• 135-02-4 ortho-anisaldehyde 
• 56-23-5 tetrachloromethane 
• 100-66-3 methoxybenzene 
• 201230-82-2 carbon monoxide 
• 4416-67-5 2-tosyloxyanisole 
• 2439-77-2 2-methoxybenzamide 
• 75-91-2 tert.-butylhydroperoxide 
• 91764-78-2 butyl (2-methoxyphenyl)methyl ether 
• 88105-15-1 N-(2-hydroxyethyl)-2-methoxybenzamide 
• 766-51-8 2-Chloroanisole 

Downstream Products

• 1392227-37-0 (E)-n-butyl 2-(3-n-butoxy-3-oxoprop-1-en-1-yl)-6-methoxybenzoate 

Relevant articles and documents

Mechanistic insight into the synergistic Cu/Pd-catalyzed carbonylation of aryl iodides using alcohols and dioxygen as the carbonyl source

Pd-catalyzed carbonylation, as an efficient synthetic approach to the installation of carbonyl groups in organic compounds, has been one of the most important research fields in the past decade. Although elegant reactions that allow highly selective carbonylations have been developed, straightforward routes with improved reaction activity and broader substrate scope remain long-term challenges for new practical applications. Here, we show a new type of synergistic Cu/Pd-catalyzed carbonylation reaction using alcohols and dioxgen as the carbonyl sources. A broad range of aryl iodides and alcohols are compatible with this protocol. The reaction is concise and practical due to the ready availability of the starting materials and the scalability of the reaction. In addition, the reaction affords lactones and lactams in an intermolecular fashion. Moreover, DFT calculations have been performed to study the detailed mechanisms. [Figure not available: see fulltext.]

Synthesis of Esters from Stable and Convenient Sulfoxonium Precursors under Catalyst- And Additive-Free Conditions

A convenient and efficient procedure for the construction of esters from stable sulfoxonium ylides and alcohols has been developed. This protocol presents a broad substrate scope and good yields of the desired esters can be isolated. Notably, no catalyst, oxidant, base or any other additive is required.

Synthesis of Hydroxybenzoic Acids and Their Esters by Reaction of Phenols with Carbon Tetrachloride and Alcohols in the Presence of Iron Catalysts

Alkyl esters of hydroxy-, methoxy-, and ethoxybenzoic and cresotic acids have been synthesized by reaction of phenols, anisole, phenetole, and cresols with carbon tetrachloride and alcohols in the presence of iron catalysts.