236401-76-6

Basic information

• Product Name: (2S,4R,5R)-2-benzoyloxy-5-(diethyl-iso-propylsilyloxy)-4-ethylhexan-3-one
• Synonyms: (2S,4R,5R)-2-benzoyloxy-5-(diethyl-iso-propylsilyloxy)-4-ethylhexan-3-one
• CAS NO: 236401-76-6
• Molecular Weight: 392.611
• Mol File: 236401-76-6.mol

Chemical Properties

• CAS DataBase Reference: (2S,4R,5R)-2-benzoyloxy-5-(diethyl-iso-propylsilyloxy)-4-ethylhexan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4R,5R)-2-benzoyloxy-5-(diethyl-iso-propylsilyloxy)-4-ethylhexan-3-one(236401-76-6)
• EPA Substance Registry System: (2S,4R,5R)-2-benzoyloxy-5-(diethyl-iso-propylsilyloxy)-4-ethylhexan-3-one(236401-76-6)

Safety Data

• Hazardous Substances Data: 236401-76-6(Hazardous Substances Data)

Upstream product

• 177905-47-4 (2S)-2-(benzyloxy)hexan-3-one 
• 236401-61-9 (2S,4R,5R)-2-benzoyloxy-4-ethyl-5-hydroxy-hexan-3-one 
• 107149-56-4 chlorodiethylisopropylsilane 

Relevant articles and documents

Total synthesis of elaiolide using a copper(l)-promoted stille cyclodimerization reaction

(equation presented) Elaiolide (2) The 16-membered macrodiolide elaiolide (2) has been prepared in 20 steps from the ketone (S)-8 in 9.3% overall yield with a diastereoselectivity of 76%. Key steps included the copper(l) thiophene-2-carboxylate promoted c