236424-93-4

Basic information

• Product Name: methyl 2,3-di-O-benzyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranoside
• Synonyms: methyl 2,3-di-O-benzyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranoside
• CAS NO: 236424-93-4
• Molecular Weight: 370.445
• Mol File: 236424-93-4.mol

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-benzyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-benzyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranoside(236424-93-4)
• EPA Substance Registry System: methyl 2,3-di-O-benzyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranoside(236424-93-4)

Safety Data

• Hazardous Substances Data: 236424-93-4(Hazardous Substances Data)

Upstream product

• 90633-95-7 methyl 2,3-bis-O-benzyl-4-O-[(4-methoxyphenyl)methyl]-α-D-glucopyranoside 
• 130523-98-7 (2S,3S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-3-(4-methoxy-benzyloxy)-tetrahydro-pyran-2-carbaldehyde 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 
• 305815-34-3 [(2R,3R,4R,5R,6S)-4,5-Bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-tetrahydro-pyran-2-yl]-methanol 
• 118545-10-1 (2S,3R,4R,5R,6R)-3,4-Bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2-methoxy-tetrahydro-pyran 
• 485386-44-5 ((2R,3R,4R,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-tert-butyl-dimethyl-silane 
• 236424-91-2 methyl 2,3-di-O-benzyl-6,7-dideoxy-4-O-(4-methoxybenzyl)-α-D-gluco-hept-6-enopyranoside 

Downstream Products

• 485386-74-1 (E)-(1S,2R,3R,4aR,6aR,8S,9R,10R,10aR,13aS)-1,2,9,10-Tetrakis-benzyloxy-3-benzyloxymethyl-8-methoxy-12,12-dimethyl-1,2,3,4a,6a,8,9,10,10a,13a-decahydro-4,7,11,13-tetraoxa-12-sila-dibenzo[a,e]cyclononene 
• 485386-56-9 (E)-(1R,2R,3S,4aR,6aR,10aS,13aR)-1,2-Bis-benzyloxy-3-methoxy-12,12-dimethyl-1,2,3,4a,6a,8,9,10,10a,13a-decahydro-4,7,11,13-tetraoxa-12-sila-dibenzo[a,e]cyclononene 
• 200621-49-4 (1R,6R,8S,9R,10S)-9,10-bis(benzyloxy)-8-methoxy-2,7-dioxabicyclo[4.4.0]dec-4-ene 
• 485386-64-9 ((2R,3R,4R,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-dimethyl-pent-4-enyloxy-silane 
• 485386-63-8 ((2R,3R,4R,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-but-3-enyloxy-dimethyl-silane 
• 485386-75-2 ((2S,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-vinyl-tetrahydro-pyran-3-yloxy)-((2R,3R,4R,5R,6S)-4,5-bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane 
• 485386-73-0 ((2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-vinyl-tetrahydro-pyran-3-yloxy)-((2R,3R,4R,5R,6S)-4,5-bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane 
• 485386-55-8 ((2R,3R,4R,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-dimethyl-((2R,3S)-2-vinyl-tetrahydro-pyran-3-yloxy)-silane 
• 485386-45-6 Allyloxy-((2R,3R,4R,5R,6S)-4,5-bis-benzyloxy-6-methoxy-2-vinyl-tetrahydro-pyran-3-yloxy)-dimethyl-silane 
• 485386-65-0 (2S,3R,4S,5R,6R)-3,4-Bis-benzyloxy-5-but-3-enyloxy-2-methoxy-6-vinyl-tetrahydro-pyran 
• 485386-66-1 (2S,3R,4S,5R,6R)-3,4-Bis-benzyloxy-2-methoxy-5-pent-4-enyloxy-6-vinyl-tetrahydro-pyran 
• 485386-67-2 (2S,3R,4S,5R,6R)-3,4-Bis-benzyloxy-5-hex-5-enyloxy-2-methoxy-6-vinyl-tetrahydro-pyran 
• 200621-48-3 methyl 4-O-allyl-2,3-di-O-benzyl-6,7-dideoxy-α-D-gluco-hept-6-enopyranoside 
• 236424-97-8 methyl 2,3-di-O-benzyl-6,7-dideoxy-4-O-propargyl-α-D-gluco-hept-6-enopyranoside 

Relevant articles and documents

Cross-metathesis and ring-closing metathesis of olefinic monosaccharides

Cross-metathesis (CM) of a variety of carbohydrate-based C-6 and olefins with related C-1 and C-6 carbohydrate-based olefins proved to be unselective. CM was selective when an unhindered straight chain olefin was coupled with a carbohydrate-based C-6 olefin. When related short chain alkenols were tethered, via a Me2Si linker, to a suitably protected carbohydrate-based C-6 olefin, good yields of ring-closed products were obtained with the second-generation Grubbs catalyst 3. A few examples where two carbohydrate-based olefinic alcohols were tethered via a Me2Si linker and subjected to ring-closing metathesis (RCM) have also been examined.

A convenient route to cis- and trans-fused bicyclic ethers by ruthenium mediated ring-closing metathesis of diene and enyne carbohydrate derivatives

A general approach towards the construction of highly functionalised pyranopyran and pyranofuran systems via Grubbs [Ru] catalysed ring-closing metatheses of neighbouring vinyl-O-allyl and vinyl-O-propargyl functions on monosaccharide scaffolds is describ