236427-86-4

Upstream product

• 4039-82-1 Benzyl propargyl ether 
• 80885-30-9 (E)-4-(benzyloxy)-2-buten-1-ol 
• 91142-50-6 4-benzyloxy-2-butyn-1-ol 
• 79271-56-0 triethylsilyl trifluoromethyl sulfonate 
• 100-39-0 benzyl bromide 
• 236427-71-7 {(2R,3S)-3-[(1S,2R)-3-Benzyloxy-1,2-bis-(tert-butyl-dimethyl-silanyloxy)-propyl]-oxiranyl}-methanol 
• 236427-72-8 (2S,3S,4S,5R)-6-Benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hexane-1,3-diol 
• 236427-73-9 (2R,3S,4S,5R)-6-Benzyloxy-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-phenylsulfanyl-hexan-3-ol 
• 236427-83-1 {(2S,6S,8S,10R,13S)-10-[2-(4-Methoxy-benzyloxy)-ethyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-acetaldehyde 
• 236427-74-0 C₃₈H₆₈O₅SSi₃ 
• 236427-82-0 2-{(2S,6S,8S,10R,13S)-10-[2-(4-Methoxy-benzyloxy)-ethyl]-13-methyl-13-triethylsilanyloxy-1,7,9-trioxa-dispiro[5.1.5.2]pentadec-2-yl}-ethanol 
• 236427-75-1 C₃₈H₆₈O₇SSi₃ 

Downstream Products

• 236427-87-5 (2R,5S,6S,8R,10S)-10-((1S,2S,3S,5S,7R)-7-Benzyloxymethyl-2-hydroxy-3-methyl-6,8-dioxa-bicyclo[3.2.1]oct-5-ylmethyl)-2-[2-(4-methoxy-benzyloxy)-ethyl]-5-methyl-1,7,9-trioxa-dispiro[5.1.5.2]pentadecan-5-ol 
• 236427-89-7 10-[7-benzyloxymethyl-2-(tert-butyl-dimethyl-silanyloxy)-3-methyl-6,8-dioxa-bicyclo[3.2.1]oct-5-ylmethyl]-5-(tert-butyl-dimethyl-silanyloxy)-2-[2-(4-methoxy-benzyloxy)-ethyl]-5-methyl-1,7,9-trioxa-dispiro[5.1.5.2]pentadecane 

Relevant academic research and scientific papers

Synthesis of the B,C,D,E,F-ring fragment of pinnatoxins

Construction of the B,C,D,E,F-ring of pinnatoxins is disclosed. Julia coupling reaction between the E,F-ring fragment (C26-C31) as the sulfone and the B,C,D-ring fragment (C10-C25) as the aldehyde proceeded smoo