23646-65-3

Upstream product

• 3006-60-8 1,3,4,6-tetra-O-acetyl-2-acetamido-2-deoxy-α,β-D-mannopyranose 
• 72-87-7 N-acetyl-D-mannosamine 
• 10378-06-0 2-methyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-mannopyrano)-[2,1:4',5']-2-oxazoline 
• 108-95-2 phenol 

Downstream Products

• 1379001-47-4 C₂₀H₂₄N₂O₁₁ 
• 570412-09-8 4-nitrophenyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-α-D-mannopyranoside 
• 1379001-48-5 o-nitrophenyl 2-acetamido-2-deoxy-α-D-mannopyranoside 
• 4291-19-4 Phenyl 2-acetamido-2-desoxy-α-D-mannopyranosid 

Relevant academic research and scientific papers

Facile synthesis of nitrophenyl 2-acetamido-2-deoxy-α-D- mannopyranosides from ManNAc-oxazoline

The synthetic procedures for a large-scale preparation of o- and p-nitrophenyl 2-acetamido-2-deoxy-α-D-mannopyranoside are described. The synthetic pathway employs the glycosylation of phenol with ManNAc oxazoline, followed by nitration of the aromatic moiety yielding a separable mixture of the o- and p-nitrophenyl derivative in a 2:3 ratio.