2372-98-7Relevant articles and documents
Molines,Wakselman
, p. 232 (1975)
Heck reaction with 3-fluoro-3-buten-2-one
Patrick, Timothy B.,Agboka, Titus Y.,Gorrell, Keith
experimental part, p. 983 - 985 (2009/04/04)
3-Fluoro-3-buten-2-one (2) is readily prepared from 1-fluoro-1-chloro-2-methoxy-2-methylcyclopropane (1) in 82% yield by heating the cyclopropane in aqueous quinoline solution. Ketone 2 reacts with aryl iodides (3) in a Heck reaction catalyzed by Pd(OAc)2 to give Z-3-fluorobenzalacetones (4) in 36-86% yield.
Novel substituted aromatic compounds
-
, (2008/06/13)
Substituted phenoxy, phenylthio and anilino compounds, intermediates therefor, synthesis thereof, and their use for the control of pests.