23740-63-8Relevant academic research and scientific papers
Studies on the Oxidation of Enamines with Molecular Oxygen. I. Oxidation of Some Piperidino Alkenes
Blau, Karla,Voerckel, V.
, p. 285 - 292 (2007/10/02)
In the autoxidation of 1-piperidinocyclohex-1-ene (1), 1-piperidinobut-1-ene (2), 3-piperidinopent-2-ene (3), and 1-piperidino-2-methyl-prop-1-ene (4) only products of an oxidative attack at the C=C-double bond are formed.Both α-aminoketones, the products of the rearrangement of primarily formed epoxides, and products of the oxidative scission of the C=C double bond are obtained.As a side reaction some hydrolysis of the starting enamines takes place.This hydrolysis proves that some water must be formed during the enamine oxidation.
