23743-24-0Relevant articles and documents
Method for enantioselective synthesis of phosphorus-stereogenic phosphines
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Page/Page column 33-36, (2012/06/16)
The present invention relates to a process for preparing an enantioenriched phosphorus-stereogenic, tertiary phosphine. Secondary phosphines are contacted with an alkyl halide and base in the presence of a chiral metal catalyst thereby producing the enantioenriched phosphorus-stereogenic, tertiary phosphine for subsequent use in homogeneous catalysis reactions.
METHOD FOR ENANTIOSELECTIVE SYNTHESIS OF PHOSPHORUS-STEREOGENIC PHOSPHINES
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Page/Page column 55-56, (2008/06/13)
The present invention relates to a process for preparing an enantioenriched phosphorus-stereogenic, tertiary phosphine. Secondary phosphines are contacted with an alkyl halide and base in the presence of a chiral metal catalyst thereby producing the enantioenriched phosphorus-stereogenic, tertiary phosphine for subsequent use in homogeneous catalysis reactions.